金禹瑞

　　中国化学会理事，中国稀土学会理事，中国晶体学会理事，《无机化学》、《结构化学》和《中国稀土学报》杂志编委、十多种国际性学术杂志(包括《美国化学会会志》、美国《无机化学》和10种国内学术杂志（包括《中国科学》、《 化学学报》、《中国化学》、《科学通报》、《高校化学学报》等）审稿人，曾担中山大学任化学与化学工程学院院长。

　　他主要从事功能金属配合物和聚合金属配合物超分子体系的分子设计、合成和结构与性能研究。目前已取得的主要研究成果有三个方面：

　　(1) 1992年起，开展“金属酶活性中心构的小分子模拟”的研究，取得具有特色的进展，合成了多种金属酶活性中心结构的新型模型化 合物并进行深入的结构与催化性质研究。

　　(2) 1994年起，开展了“具有光电子性能的簇合物与聚合物研究”，创立合成含铜与其它金属的异多核配合物的独特方法，设计和组装新 型异多核金属配合物，在复杂异多核金属配合物的分子设计与合成方面取得新的突破，成功建立起系列铜－稀土18核簇合物及其它铜－稀土异 多核配合物的新颖制备方法，开展复杂金属配合物体系的磁性及光电性质研究，为异金属功能配合物在分子光电器件中的应用研究提供了新的 基础。

　　（3）成功利用桥连配体与金属离子作为模块组装了大量的、具有不同框架结构的聚合金属配合物，并通过超分子作用等调控聚合物的框架 结构，获得系列具有新颖结构和发光功能等功能的新型有机—金属聚合物，为此类新型无机—有机杂化材料的研制提出新的研究思路和方向。

　　1993年以来，主持包括国家杰出青年科学基金和国家基金重点项目等10多项国家和省部级科学基金课题。迄今在国内外学术杂志上发表学 术论文230多篇，其中在包括国际第一流的化学杂志《美国化学会会志》、德国《应用化学》、《欧洲化学》等知名学术刊物发表200多篇。部 分论文已被同行在国际性学术杂志上引证1160多次。根据国家科委情报中心的统计，1996年金禹瑞在国际上发表（《SCI》收录）的论文居全国个人排行榜第五位，1997年国际论文被引用篇数全国个人排位第三名。1999年国际论文被引用篇数全国个人排位第三名。曾应邀在13次国际性 和17次全国性学术会议上作邀请报告。在教学方面，他曾讲授《结构化学》、《波谱化学》、《X射线单晶结构分析》和《金属配合物的现代研究方法》、《现代无机化学》、《 配位化学》等本科生、研究生课程。指导博士后、博士生、硕士生等的科研工作，其中7名博士生和6名硕士生已毕业并获得相应学位。他指导 的一名博士生的学位论文被评为“全国优秀博士论文”（2001年）。

　　由于他在科研和教学等方面取得的成绩，1996年获国家杰出青年科学基金的资助。1997年获第五届“中国青年科技奖”，首届“广东省优 秀青年科学家奖”。1998年，获广东省自然科学奖一等奖（第一完成人）、广东省“十大杰出青年”称号。入选国家“百千万”人才工程97年 度第一、二层次人选。1999年获得求是科学基金会“杰出青年学者奖”。2000年获得中国高等学校科学技术奖二等奖（第三完成人）。2002年 获得中国高等学校科学技术奖二等奖（第一完成人）。

　　   近年作为通讯作者发表的部分论文目录：

　　   2009

　　1. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal Zhang, J.-P.;    Chen, X.-M.,    J. Am. Chem. Soc. 2008, ja-2008-089872.

　　2. Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold interpenetration: (3,5) connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.;    Chen, X.-M.,    Cryst. Growth Des. 2009, cg-2008-01308u.

　　3. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.;    Chen, X.-M.,   Inorg. Chem. 2009, ic-2008-02446m.

　　4. A spin-frustrated complex, [FeIIFeIII(trans-1, 4-cyclohexanedicarboxylate)1.5]∞: Interplay between single-chain magnet behavior and magnetic ordering Zheng, Y.-Z.; Xue, W.; Zhang, W.-X.; Tong, M. L.;    Chen, X.-M.; Grandjean F.; Long G. J.; Ng, S. W.; Panissod P.; Drillon M.,   Inorg. Chem. 2009, 48, 2028u20132042.

　　5. Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue W.;    Chen, X.-M.;   Dalton Trans 2009, 1396-1406.

　　6. Syntheses, structures and sorption properties of two framework-isomeric porous copper coordination polymers Xue D.-X.; Lin, J.-B.; Zhang, J.-P.;    Chen, X.-M.,    CrystEngComm 2009, 11, 183-188.

　　   2008

　　7. Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.;    Chen, X.-M.; Zheng, S.-L.,    Inorg. Chem. 2008, 47, 11202u201311211.

　　8. Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.;   Chen, X.-M.,    Cryst. Growth Des. 2008, 8, 4559-4563.

　　9. Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.;   Chen, X.-M.,   Cryst. Growth Des. 2008, 8, 3673u20133679.

　　10. (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.;   Chen, X.-M.,    CrystEngComm 2008, 10, 1770-1776.

　　11. Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.;    Chen, X.-M.; Ng, S.W.,    Chem. Commun. 2008, 4019u20134021.

　　12. Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N., Xue, W., Zhang, W.-X.,    Chen, X.-M.,    Chem. Mater. 2008, 20, 5345u20135350.

　　13. Pentanuclear and heptanuclear metal helicates by self-assembly of d metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X., Zhang, J.-P., Lin, Y.-Y.,   Chen, X.-M.,   Inorg. Chem. 2008, 47, 7389-7395..

　　14. Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F., Zhang, Y.-B., Cheng, X.-N.,    Chen, X.-M.,    CrystEngComm 2008, 10, 753u2013758.

　　15. A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition Zheng, Y.-Z., Xue, W., Tong, M.-L., Zhang, W.-X.,    Chen, X.-M., Grandjean F.; Long G. J.,    Inorg. Chem. 2008, 47, 4077-4087.

　　16. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.;    Chen, X.-M.,    J. Am. Chem. Soc. 2008, 130, 6010u20136017.

　　17. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue W.; Zheng, S.-L.; Tong, M.-L. ;    Chen, X.-M.,   Adv. Mater. 2008, 20, 1534u20131538.

　　18. Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.;   Chen, X.-M.; Wang, H.-Z.,    Chem. Commun. 2008, 1551-1553.

　　19. Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.;    Chen, X.-M.,    Inorg. Chem. 2008, 47, 1346-1351.

　　   2007

　　20. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin canting antiferromagnetic layer Cheng, X.-N.; Zhang, W.-X.;    Chen, X.-M.,    J. Am. Chem. Soc. 2007, 129, 15738-15739.

　　21. Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology, Hu, S.; Zhang, J.-P.; Tong, M.-L.;    Chen, X.-M.;    Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289.

　　22. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.;    Chen, X.-M.; Grandjean, F.; Long, G. J.,    Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China)

　　23. From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.;    Chen, X.-M.,    Inorg. Chem. 2007, 46, 6437-6443.

　　24. A tetracarboxylateu2013bridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.;    Chen, X.-M.,    Cryst. Growth Des. 2007, 7, 1332-1336.

　　25. Unprecedented (3,9)-connected (4.6)3(4.6.8) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.;    Chen, X.-M.,    Cryst. Growth Des. 2007, 7, 980u2013983.

　　26. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.;   Chen, X.-M.,    Adv. Mater. 2007, 19, 1494u20131498.

　　27. Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry    Chen, X.-M.; Tong, M.-L.,    Acc. Chem. Res. 2007, 40, 162-170.

　　28. In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.;    Chen, X.-M.,    Inorg. Chem. 2007, 46, 1135-1143.

　　   2006

　　29. Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.;   Chen, X.-M.,    Cryst. GrowthDes. 2006, 6, 2739-2746.

　　30. A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.;   Chen, X.-M.,    Dalton Trans. 2006, 5294-5303.

　　31. Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.;    Chen, X.-M., Gao, S.    Inorg. Chem. 2006, 45, 7069-7076.

　　32. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.;    Chen, X.-M.,    Angew. Chem. Int. Ed. 2006, 45, 6310-6314.

　　33. The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]￥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.;    Chen, X.-M.,    Chem. Commun. 2006, 3603-3605.

　　34. Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.;    Chen, X.-M.,   Cryst. Growth Des. 2006, 6, 1684-1689.

　　35. Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate Huang, X.-C.; Li, D.;    Chen, X.-M.,   CrystEngComm 2006, 8, 351-355.

　　36. One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.;    Chen, X.-M.,    Cryst. Growth Des. 2006, 6, 1194-1198.

　　37. (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.;   Chen, X.-M.,    Chem. Commun. 2006, 1689-1699.

　　38. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.;    Chen, X.-M.,    Angew. Chem. Int. Ed. 2006, 45, 1557-1559.

　　39. From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.;    Chen, X.-M.,    Cryst. Growth Des. 2006, 6, 519u2013523.

　　40. Coexistence of spin frustration and long-range magnetic ordering in a triangular Co3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.;    Chen, X.-M.,    Chem. Commun. 2006, 165u2013167.

　　   2005

　　41. Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; and   Chen, X.-M.,    Inorg. Chem. 2005, 44, 8285-8292.

　　42. Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.;    Chen, X.-M.,    Dalton Trans. 2005, 3681-3685.

　　43. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.;    Chen, X.-M.,   J. Am. Chem. Soc. 2005, 127, 14162-14163.

　　44. Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.;    Chen, X.-M.,    Cryst. Growth Des. 2005, 5, 1609-1616.

　　45. Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.;    Chen, X.-M.,    Inorg. Chem. 2005, 44, 4270-4275.

　　46. A solvothermally in-situ generated mixed-ligand approach for NLO-active metalu2013organic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.;    Chen, X.-M.,   Inorg. Chem. 2005, 44, 4148-4149.

　　47. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets Zeng, M.-H.;Zhang, W.-X.; Sun, X.-Z.;    Chen, X.-M.,   Angew. Chem. Int. Ed. 2005, 44, 3079-3082.

　　48. Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.;    Chen, X.-M.,   Inorg. Chem. 2005, 44, 3146-3150.

　　49. Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.;    Chen, X.-M.,    Chem. Commun. 2005, 2232u20132234.

　　50. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.;    Chen, X.-M.,    J. Am. Chem. Soc. 2005, 127, 5495-5506.

　　51. Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.;    Chen, X.-M.,    Cryst. Growth Des. 2005, 5, 695u2013700.

　　52. Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.;    Chen, X.-M.,   Cryst. Growth Des. 2005, 5, 617-622.

　　53. Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.;    Chen, X.-M.,   Chem. Commun. 2005, 1258u20131260. (Hot Paper)

　　54. (Review Article) Metal-organic molecular architectures with 2,2u2019-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.;    Chen, X.-M.,    Coord. Chem. Rev. 2005, 249, 545u2013565.

　　55. Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = Gd or Nd) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.;    Chen, X.-M.,    Inorg. Chem. 2005, 44, 559-565.

　　56. Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.;    Chen, X.-M.,    Dalton Trans. 2005, 424-426.(Hot Paper, Highlighted in Chemical Science)

　　57. Metallophilicity versus p-p interactions: Ligand-unsupported argentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = Cu or Ag, L = tridentate ligand) Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.;    Chen, X.-M.,   Chem. Eur. J. 2005, 11, 552-561.

　　   2004

　　58. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates Huang, X.-C.; Zhang, J.-P.;    Chen, X.-M.,    J. Am. Chem. Soc. 2004, 126, 13218-13219.

　　59. (Cover Paper) Crystal-to-crystal transformations of a microporous metal-organic laminated framework triggered by guest exchange, dehydration and readsorption Zeng, M.-H.; Feng, X.-L.;    Chen, X.-M.,    Dalton Trans. 2004, 2217-2223. (Highlighted in Chem. Sci.)

　　60. Syntheses, structures and photoluminescent properties of three silver(I) cluster-based coordination polymer with aromatic heterocycle carboxylates Yang, J.-H.; Zheng, S.-L.;    Chen, X.-M.,    Cryst. Growth Des. 2004, 4, 831-836.

　　61. Syntheses, structures, and photoluminescence studies of [2:2] metallomacrocyclic silver(I) complexes with 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)benzene Ren, C.-X.; Ye, B.-H.; He, F.; Cheng, L.;   Chen, X.-M.,    CrystEngComm 2004, 6, 200-207.

　　62. A single-source approach to Bi2S3 and Sb2S3 nanorods via hydrothermal treatmentXie, G.; Qiao, Z.-P.; Zeng, M.-H.;    Chen, X.-M.; Gao, S.-L.,    Cryst. Growth Des. 2004, 4, 513-516.

　　63. Two new mixed-valence Cu(I,II) imidazolate coordination polymers: Metal-valence tuning approach for new topologic structures Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.;    Chen, X.-M.,   Chem. Commun. 2004, 1100-1101.

　　64. Syntheses, structures, photoluminescence and theoretical studies of d metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate Zheng, S.-L.; Yang, J.-H.; Yu, X.-L.;   Chen, X.-M., W.-T. Wong,    Inorg. Chem. 2004, 43, 830-838.

　　65. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.;    Chen, X.-M.,    Angew. Chem. Int. Ed. 2004, 43, 206-209.

　　   2003

　　66. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly Zheng, S.-L.; Tong, M.-L.;    Chen, X.-M.,    Coord. Chem. Rev. 2003, 246, 185-202.

　　67. Syntheses, structures, photoluminescence and theoretical studies of a novel class of d metal complexes of 1H-[1,10]phenanthrolin-2-one Zheng, S.-L.; Zhang, J.-P.;    Chen, X.-M.; Huang, Z.-L.; Lin, Z.-Y.; Wong, W.-T.,   Chem. Eur. J. 2003, 9, 3888-3896.

　　68. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.;   Chen, X.-M.,    J. Am. Chem. Soc. 2003, 125, 6882-6883.

　　   2002

　　69. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions    Chen, X.-M.; Liu, G.-F.,    Chem. Eur. J. 2002, 8, 4811-4817.

　　70. Pseudo-polyrotaxane and b-sheet layer-based three-dimensional coordination polymers constructed with silver(I) salts and flexible pyridyl-type ligands Tong, M.-L.; Wu, Y.-M.; Ru, J.;    Chen, X.-M., H.-C. Chang, Kitagawa, S.,    Inorg. Chem. 2002, 41, 4846-4848.

　　71. Metal cation-supported supramolecular crown ethers featuring hydrogen-bonded tetrameric unit of 2-hydroxy pyridines Tong, M.-L.; Lin, Z.-J.; Li, W.; Zheng, S.-L.;    Chen, X.-M.,    Cryst. Growth Des. 2002, 2, 443-448.

　　72. Microwave-assisted elemental-direct-reaction route to nanocrystalline copper chalcogenides CuSe and Cu2Te Zhang, Y.; Qiao, Z.-P.;   Chen, X.-M.,   J. Mater. Chem. 2002, 12, 2747-2748.

　　73. Syntheses, crystal structures and physical properties of dinuclear copper(I) and tetranuclear mixed valence copper(I,II) complexes with hydroxylated bipyridyl-like ligands Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Lee, H.K.; Luo, L.; Li, J.-H.; Tong, Y.-X.;    Chen, X.-M.,    Chem. Eur. J. 2002, 8, 3187-3194.

　　74. Interlocking of molecular rhombi into 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)]2×H2O (bpa = biphenyl-4,4￠-dicarboxylate, phen = 1,10-phenanthroline)Liu, G.-F.; Ye, B.-H.; Ling, Y.-H.;    Chen, X.-M.,   Chem. Commun. 2002, 1442-1443.

　　75. A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions Tao, J.; Zhang, Y.; Tong, M.-L.;    Chen, X.-M., Yuen, T.; Lin, C.L.; Huang, X.-Y.; Li, J.,   Chem. Commun. 2002, 1342-1343.

　　76. Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form Tong, M.-L.; Lee, H.K.; Tong, Y.-X.; Zheng, S.-L.; Shi, J.-X.;    Chen, X.-M.,    Dalton Trans. 2002, 1727-1734.

　　77. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes Zhang, X.-M.; Tong, M.-L.;    Chen, X.-M.,    Angew. Chem. Int. Ed. 2002, 41, 1029-1031.

　　78. One-pot monomer self-assembly route to thin coatings core/shell PbS/poly(methyl methacrylate) nanocomposites Qiao, Z.-P.; Xie, G.; Huang, J.-M.; Zhao, S.-Y.;    Chen, X.-M.,   J. Mater. Chem. 2002, 12, 611u2013613.

　　79. Self-assembly of new three-dimensional molecular architectures constructed from silver(I)-hexamethylenetetramine layers with supramolecular interactions Zheng, S.-L.; Tong, M.-L.;    Chen, X.-M.;Ng, S.W.,   Dalton Trans. 2002, 360-364.

　　   2001

　　80. Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dicarboxylates with hexamethylenetetramine exhibiting unique metal-p interaction Zheng, S.-L.; Tong, M.-L.; Tan, S.-D.; Wang, Y.; Shi, J.-X.; Tong, Y.-X.; Lee, H.K.;    Chen, X.-M.,    Organometallics 2001, 20, 5319-5325.

　　81. Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits Chen, H.-J.; Mao. Z.-W.; Gao, S.;    Chen, X.-M.   Chem. Commun. 2001, 2320-2321.

　　82. A blue photoluminescent three-dimensional coordination polymer constructed with helical [Zn3(μ3-OH)(μ2-OH)]￥ chains and mixed organic ligandsTao, J.; Tong, M.-L.; J.-X. Shi,    Chen, X.-M.,   Inorg. Chem. 2001, 40, 6328-2330.

　　83. A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates Cai, J.-W.; Chen, C.-H.; Feng, X.-L.; Liao, C.-Z.;    Chen, X.-M.,   Dalton Trans. 2001, 2370u20132375.

　　84. The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2] Zhang, X.-M.; Tong, M.-L.; Feng, S.-H.;    Chen, X.-M.,    Dalton Trans. 2001, 2069-2070.

　　85. Syntheses and structures of three two-dimensional silver(I)-hexamethylenetetramine coordination polymers with new topologic motifs Zheng, S.-L.; Tong, M.-L.; Zhu, H.-l.; Fang, Y.;    Chen, X.-M.,    Dalton Trans. 2001, 2049-2053.

　　86. Toward designed assembly of microporous coordination networks constructed from the silver(I)-hexamethylenetetramine layers Zheng, S.-L.; Tong, M.-L.; Fu, R.-W.;    Chen, X.-M.,    S.W. Ng, Inorg. Chem. 2001, 40, 3562-3569.

　　87. Hydrogen bonds induced change of geometry and crystallized form of copper(II) complexes: syntheses and crystal structure of copper(II) complexes with Schiff-base ligands containing two imidazolyl groupsLong, L.-S.; Cai, J.-W.; Ren, Y.-P.; Tong, Y.-X.;    Chen, X.-M.; Ji, L.-N.; Huang, R.-B.; Zheng, L.-S.,    Dalton Trans. 2001, 845-849.

　　88. A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4￠-bpy)]n layers and V4O12pillars Tao, J.; Zhang, X.-M.; Tong, M.-L.;    Chen, X.-M.,   Dalton Trans.2001,770-771.

　　89. Syntheses and structures of six chain-, ladder- and grid-like coordination polymers constructed from m-hexamethylenetetramine and silver salts Zheng, S.-L.; Tong, M.-L.;    Chen, X.-M.,    Dalton Trans. 2001, 586-592.

　　90. Syntheses and crystal structures of four metal-organic coordination networks constructed form cadmium(II) thiocyanate and nicotinic derivatives with hydrogen bonds Yang, G.; Zhu, H.-G.; Liang, B.-H.;    Chen, X.-M.,   Dalton Trans. 2001, 580-585.

　　91. Syntheses and crystal structures of five two-dimensional networks constructed from staircase-like silver(I) thiocyanate chains and bridging polyamines Ren, C.-X.; Zhu, H.-L.; Yang G.;   Chen, X.-M.,    Dalton Trans. 2001, 85-90.

　　   2000

　　92. Influence of ligand backbones and counter ions on structures of helical silver(I) complexes with di-Schiff bases derived from phthalaldehydes and diamine Zhu, H.-L.; Tong, Y.-X.;   Chen, X.-M.,   J. Chem. Soc.,    Dalton Trans. 2000, 4182-4186.

　　93. Hydrothermal synthesis and crystal structures of [M(tp)(4,4u2019-bipy)] (M = Co(II), Cd(II) and Zn(II)): Three-dimensional coordination frameworks constructed with mixed terephthalate (tp) and 4,4u2019 bipyridine (4,4u2019-bipy) ligands Tao, J.; Tong, M.-L.;    Chen, X.-M.,    J. Chem. Soc.,   Dalton Trans. 2000, 3669-3674.

　　94. Blue photoluminescent zinc co-ordination polymers with supertetranuclear coresTao, J.; Tong M.-L.; Shi, J.-X.;    Chen, X.-M., Ng, S.W.,    Chem. Commun. 2000, 2043-2044.

　　95. An octanuclear copper(II) complex self-assembled with divalent gem-diol form anion of di-2-pyridyl ketone (dpd-2H) and 2-hydroxylpyridine. Synthesis, crystal structure and properties of [Cu8(dpd-2H)4(m2-O2CMe)4{2-(OH)C5H4N}4](ClO4)4×4H2O Tong, M.-L.; Lee, H. K.; Tong, Y.-X.;   Chen, X.-M.; Mak, T.C.W.,    Inorg. Chem. 2000, 39, 4666-4669.

　　96. Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different small simple silver(I) salts Tong, M.-L.; Zheng, S.-L.;    Chen, X.-M.,    Chem. Eur. J. 2000, 6, 3729-3638.

　　97. Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]×6H2O Zhang, X.-M.; Tong, M.-L.;    Chen, X.-M.,    Chem. Commun. 2000, 1817-1818.

　　98. Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, structures and non-linear optical properties of [4,4u2019-bipyH2][M(NCS)4] (M = Mn, Co and Zn; 4,4u2019-bipy = 4,4u2019-bipyridine) Chen, H.-J.; Zhang, L.-Z.; Cai, Z.-G.; Yang, G.;   Chen, X.-M.,    J. Chem. Soc. Dalton Trans. 2000, 2463-2467.

　　99. Influence of the counter-ions and ligands on structures of silver(I) helicates with di-Schiff bases containing imidazole groups Yang, S.-P.;    Chen, X.-M.; L.-N. Ji,    J. Chem. Soc., Dalton Trans. 2000, 2337-2344.

　　100. Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4u2019-bpy)3(H2O)2(phba)2](NO3)2×4H2O (M = Cu2+ or Co ; 4,4u2019-bpy = 4,4u2019-bipyridine; phba = 4-hydroxybenzoate) Tong, M.-L.; Chen, H.-J.;    Chen, X.-M.,   Inorg. Chem. 2000, 39, 2235-2238.

　　101. Anionic and neutral metal-4,4u2019-bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4u2019-bipyridineTong, M.-L.;    Chen, X.-M.,   CrystEngCom 2000, 1.

　　   1999

　　102. A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4u2019-bipyridine)2(H2O)4] cations and rich solvate 4,4u2019-bipyridine molecules throughhydrogen- bonding and p-p interactions Tong, M.-L.; Lee, H. K.;    Chen, X.-M.; Huang, R.-B.; Mak, T.C.W.,   J. Chem. Soc. Dalton Trans. 1999, 3657-3659.

　　103. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties Tong, M.-L.;    Chen, X.-M.; Ye, B.-H.; Ji,    L.-N.Angew. Chem. Int. Ed. 1999, 38, 2237-2240.

　　104. Synthesis and structures of carboxylate-bridged polynuclear copper(II)-lanthanide(III) complexes [CuLn(pyridinioacetate)5(H2O)5](ClO4)5·2H2O and [Cu3Nd2(pyridinioacetate)10(NO3)2(H2O)8](ClO48·4H2O Yang, Y.-Y.; Wu, Y.-L.; Long, L.-S.;    Chen, X.-M.,    J. Chem. Soc., Dalton Trans. 1999, 2005-2008.

　　105. Synthesis, crystal structures and properties of copper(II) complexes of Schiff base derivativescontaining imidazole and b-alanine groups Long, L.-S.; Yang, S.-P.; Tong, Y.-X.; Mao, Z.-W.;    Chen,X.-M.; Ji, L.-N.   J. Chem. Soc., Dalton Trans. 1999, 1999-2004.

　　106. Two- and three-dimensional non-interpenetrating open-networks self-assembled by m4 hexamethylene-tetramine (hmt). Syntheses and structures of [Ag2(m4-hmt)(SO4)(H2O)]×4H2O and [Ag2(m4-hmt)(m2-O2CMe)](MeCO2)×4.5H2O Tong, M.-L.; Zheng, S.-L.;    Chen, X.-M.,    Chem. Commun. 1999, 561-562.

　　   1998

　　107. Synthesis, structures and magnetic properties of carboxylate-bridged tetranuclear copper(II)-lanthanoid(III) complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10·2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8   Chen, X.-M.; Wu, Y.-L.; Yang, Y.-Y; Aubin, S.M.J.; Hendrickson,   D.N. Inorg. Chem. 1998, 37, 6186-6191.

　　108. Helical silver(I)-2,4'-bipyridine chains organized into 2-D networks by metal-counterion or metal- metal bonding. Structures of [Ag(2,4'-bipyridine)]X (X = NO or ClO) Tong, M.-L.;    Chen, X.-M.; Ye, B.-H.;Ng, S.W.,    Inorg. Chem. 1998, 37, 5278-5281.

　　109. Clathration of two-dimensional coordination polymers: Syntheses and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2](ClO4)4×(4,4'-H2bpy) (M = Cd, Zn, bpy = bipyridine)Tong, M.-L.; Ye, B.-H.; Cai, J.-W.;    Chen, X.-M., Ng, S.W.,    Inorg. Chem. 1998, 37, 2645-2650.

　　110. A novel two-dimensional rectangular network. Synthesis and structure of {[Cu(4,4'-bpy)(pyz)(H2O)2](PF6)2}n (4,4'-bpy = 4,4'-bipyridine, pyz = pyrazine) Tong, M.-L.; Yu, X.-L.;    Chen, X.-M.; Mak, T.C.W., J. Chem. Soc.,    Dalton Trans. 1998, 5-6.

　　   1994 - 1997

　　111) The first metal-encapsulating star polysulphoxide incorporating 2-amino-1,3,4-thiadiazoleYang, C.;    Chen, X.-M.; Lu, X.-Q.; Zhou, Q.-H.; Yang, Y.-S.,    J. Chem. Soc.,    Chem. Commun. 1997, 2041-2042.

　　112. Model complexes for the carboxylate-histidine-metal triad systems in metalloenzymes. Synthesis, crystal structures and spectroscopic properties of [M(Him)2(O2CMe)2] (M = ZnII or CoII, Him = imidazole).    Chen, X.-M.; Ye, B.-H.; Huang, X.-C.; Xu, Z.-T.,   J. Chem. Soc., Dalton Trans. 1996, 3465-3468.

　　113. Novel octadecanuclear copper(II)-lanthanoid(III) clusters. Synthesis and structures of [Cu12Ln6(m3-OH)24(O2CCH2CH2NC5H5)12(H2O)16(m12-ClO4)](ClO4)17·16H2O (Ln = Gd or Sm)   Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Huang, X.-Y.,    J. Chem. Soc.,    Dalton Trans. 1996, 2443-2448.

　　114. Synthesis, crystal structure and luminescence properties of a europium(III) complex with a new planar aromatic tridentate N3 ligand Yang, C.;    Chen, X.-M.; Zhang, W.-H.; Chen, J.; Yang, Y.-S.; Gong, M.-L.,   J. Chem. Soc., Dalton Trans. 1996, 1767-1768.

　　115. Synthesis and structure of a novel carboxylate-bridged heterometallic copper(II)-gadolinium(III) complex    Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J.,   J. Chem. Soc.,   Dalton Trans. 1996, 2181-2182.

　　116. Synthesis, structure and magnetic properties of a singly carboxylato-bridged dinuclear Mn(II) complex    Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T.C.W.,   J. Chem. Soc.,   Dalton Trans. 1995, 4001-4004.

　　117. Polynuclear Cu12-M6 (M = Y, Nd or Gd) complexes encapsulating a ClO4u2013 anion: [Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)    Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N.,    J. Am. Chem. Soc. 1995, 117, 9600-9601.

　　118. A model complex for the carboxylate-histidine-zinc system in zinc enzymes. Crystal structure of [Zn(Him)2(MeCO2)2] (Him = imidazole)   Chen, X.-M.; Xu, Z.-T.; Huang, X.-C.,    J. Chem. Soc.,    Dalton Trans. 1994, 2331-2332.

　　119. A dinuclear zinc complex of biological relevance. Crystal structure of [Zn2(bpy)2(MeCO2)3]ClO4   Chen, X.-M.; Tong, Y.-X.; Mak, T.C.W.,    Inorg. Chem. 1994, 33, 4586-4588.